I've been mixing vitamin supplements and gutloads for a number of years now, although I've yet to settle on a final recipe even after all this time. Two grains that are worth looking at, but which aren't as widely available as others, are Fonio and Teff. Fonio is especially popular amongst bird-keepers, and if you've ever seen a flock of birds decimate a cup of Fonio seconds after it was introduced into their aviary you'll understand why it's so popular amongst aviculturists. Fonio has tonic properties, and it's generally well accepted by roaches and various worms (I've also had good success feeding it to locusts, but I don't think they're widely used as feeders in the US.) Teff is generally regarded as the most nutritious of all grains, and has the higher calcium content than other grains I believe. Apart from Fonio and Teff, I mostly use the sprouted forms of other grains, they have a higher protein content than un-sprouted grains, and the sprouting process itself lowers the level of phytic acid found in the grains. I use: Amaranth Sprouts; sprouted Barley (brand name Activated Barley); Buckwheat Sprouts; Chia Sprouts; Flaxseed Sprouts and Sunflower Sprouts (which contain all known vitamins). These provide good levels of Amino Acids, Fatty Acids, Fibre and a range of B vitamins. If you really want to up the protein content you can add Brown Rice Protein and Hemp. Rice has a strongly negative Calcium: Phosphorous ratio though, so you want to add some high CA foods to offset this. Nutritionally Hemp is very good but it isn't always that palatable, so I only mix in small quantities. I also mix in Carob powder because of it's high Calcium content.
In addition to the aforementioned seeds and grains, I use Spirulina and Chlorella, as well as Hydrilla and Dunaliella algae. Hydrilla has one of the highest levels of Calcium you can find in any food and Dunaliella is known as the richest source of carotenoids. Sometimes I mix in small quantities of Barley Grass and Wheat Grass; nutritionally these are very good, but you have to be careful because they are also very rich and can cause digestive upset if too much is fed.
Other foods that I include regularly are: Goji Berry powder; Hawthorn Berry powder and Cayenne Pepper, these two food together increase circulation and enhance the availability of all other foods they are mixed with; Jarrah Tree Pollen and Noni Fruit, which acts as an enzyme activator and will increase assimilation of other foodstuffs.
Kindest regards,
Alex